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Triaminoguanidine is a kind of non-azide nitrogen-rich flammable compound, which has some advantages of high nitrogen, good thermal stability, and high positive formation enthalpy, etc.

摘要三氨基胍非叠氮类、富氮型、可燃性化合,其系列含能化合具有高的、热稳定性好、氮含量高等特点。

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So, the formula for enthalpy is usually written as change in enthalpy.

因此,焓的公写成焓变。

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It's analogous to the standard enthalpy of formation that we use to calculate change in enthalpy.

它类似于我们用来计算焓变的标准生成焓。

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The law itself says nothing about the standard enthalpy of formation.

该定律本身并未提及标准生成

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Change in enthalpy is equal to the heat gained or lost by the system.

变等于系统获得或损失的热量。

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Like enthalpy and entropy, we can't directly the free energy change of the whole reaction.

和熵一样, 我们不能直接表示整个反应的自由能变化。

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So I guess in the capital H for enthalpy does kinda make sense.

所以我在大写的 H 中表示确实有点道理。

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Why enthalpy change is different from heat, even though they turn out to be pretty much the same anyway.

为什变与热不同, 尽管事实证明它们几乎是一样的。

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Like enthalpy or entropy, Gibbs free energy is a state function, so it can be calculated the same way.

或熵一样, 吉布斯自由能是一个状态函数, 因此可以用相同的方计算。

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Well no, because you don't even know why enthalpy is so cool.

嗯,不,因为你甚至不知道为什

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And we measure enthalpy with a weird little science called calorimetry.

我们用一种叫做量热法的奇怪小科学来测量

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Those bonds are nothing but energy, and using enthalpy, we can measure how much energy they have.

些键只不过是能量, 使用我们可以测量它们有多少能量。

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These measurements are done at standard conditions, which we discussed in the enthalpy and entropy episodes.

些测量是在标准条件下完成的, 我们在和熵情节中对此进行了讨论。

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So, I wonder how that compares to the amount we would predict using Hess's Law and the standard enthalpy of formation?

所以,我知道与我们使用赫斯定律和标准生成预测的量相比如何?

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Hess' Law is often stated in terms of standard enthalpies of formation.

赫斯定律用标准生成来表述。

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As long as you start with the same reactants and end with the same products, the enthalpy change is the same.

只要您从相同的反应物开始并以相同的产物结束, 变就相同。

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Thanks to many hardworking chemists, the standard enthalpy of formation has been measured for hundreds of compounds.

感谢许多辛勤工作的化学家,已经测量了数百种化合物的标准生成

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And I'm very happy the inventors knew how to calculate the enthalpy change of chemical reactions.

我很高兴发明者知道如何计算化学反应的变。

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Hopefully that sounds like fun because more about the ins and outs of this are coming in an episode on how to measure enthalpy.

希望听起来很有趣,因为有关如何测量的一集中将详细介绍方面的来龙去脉

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A large change in enthalpy can determine the direction of a free energy change, even if the entropy changes in the opposite direction, and vice versa.

的大变化可以决定自由能变化的方向,即使熵的变化方向相反, 反之亦然。

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Note that the standard enthalpy is in kilojoules while the standard entropy is in joules per Kelvin.

请注意,标准的单位是千焦耳, 而标准熵的单位是焦耳每开尔文。

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